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We obtained ultraviolet and optical spectra for nine M dwarfs across a range of rotation periods to determine whether they showed stochastic intrinsic variability distinguishable from flares. The ultraviolet spectra were observed during the Far Ultraviolet M-dwarf Evolution Survey Hubble Space Telescope program using the Space Telescope Imaging Spectrograph. The optical observations were taken from the Apache Point Observatory 3.5 m telescope using the Dual Imaging Spectrograph and from the Gemini South Observatory using the Gemini Multi-Object Spectrograph. We used the optical spectra to measure multiple chromospheric lines: the Balmer series from Hαto H10 and the CaiiH and K lines. We find that after excising flares, these lines vary on the order of 1%–20% at minute-cadence over the course of an hour. The absolute amplitude of variability was greater for the faster rotating M dwarfs in our sample. Among the five stars for which we measured the weaker Balmer lines, we note a tentative trend that the fractional amplitude of the variability increases for higher-order Balmer lines. We measured the integrated flux of multiple ultraviolet emission features formed in the transition region: the Nv, Siiv,and Civresonance line doublets, and the Ciiand Heiimultiplets. The signal-to-noise ratio of the UV data was too low for us to detect nonflare variability at the same scale and time cadence as the optical. We consider multiple mechanisms for the observed stochastic variability and propose both observational and theoretical avenues of investigation to determine the physical causes of intrinsic variability in the chromospheres of M dwarfs.

The upcoming deployment of the James Webb Space Telescope will dramatically advance our ability to characterize exoplanet atmospheres, both in terms of precision and sensitivity to smaller and cooler planets. Disequilibrium chemical processes dominate these cooler atmospheres, requiring accurate photochemical modeling of such environments. The host star’s UV spectrum is a critical input to these models, but most exoplanet hosts lack UV observations. For cases in which the host UV spectrum is unavailable, a reconstructed or proxy spectrum will need to be used in its place. In this study, we use the MUSCLES catalog and UV line scaling relations to understand how well reconstructed host star spectra reproduce photochemically modeled atmospheres using real UV observations. We focus on two cases: a modern Earth-like atmosphere and an Archean Earth-like atmosphere that forms copious hydrocarbon hazes. We find that modern Earth-like environments are well-reproduced with UV reconstructions, whereas hazy (Archean Earth) atmospheres suffer from changes at the observable level. Specifically, both the stellar UV emission lines and the UV continuum significantly influence the chemical state and haze production in our modeled Archean atmospheres, resulting in observable differences in their transmission spectra. Our modeling results indicate that UV observations of individual exoplanet host stars are needed to accurately characterize and predict the transmission spectra of hazy terrestrial atmospheres. In the absence of UV data, reconstructed spectra that account for both UV emission lines and continuum are the next best option, albeit at the cost of modeling accuracy.

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability¹. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program^2,3found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO₂) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M_J) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. ⁴). The most plausible way of generating SO₂in such an atmosphere is through photochemical processes^5,6. Here we show that the SO₂distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations⁷with NIRSpec PRISM (2.7σ)⁸and G395H (4.5σ)⁹. SO₂is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H₂S) is destroyed. The sensitivity of the SO₂feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO₂also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.